Electrochemical Reactions
نویسندگان
چکیده
منابع مشابه
Thermodynamics of Electrochemical Reactions
The wish to determine thermodynamic data of electrochemical reactions and of the involved compounds is one of the most important motivations to perform electrochemical measurements. After calorimetry, electrochemistry is the second most important tool to determine thermodynamic data. Although ab initio quantum chemical calculations can be used for the calculation of thermodynamic data of small ...
متن کاملElectrochemical reactions and ionization processes.
Electrochemical or photo-electrochemical reactions in both electrospray ionization and laser desorption ionization are discussed stressing the role of the electrode reaction in influencing the ionization process. In particular, upon application of a high voltage during electrospray ionization, the emitter includes a working electrode, where redox reactions are observed, such as electro-generati...
متن کاملSurface reactions on demand: electrochemical control of SAM-based reactions.
Self-assembled monolayers (SAMs) are well-ordered, single-molecule-thick structures in two dimensions, which form spontaneously at interfaces (usually at solid surfaces). SAMs have been used for controlling physical properties of interfaces, such as wetting, adhesion, lubrication, and corrosion, as well as understanding fundamental aspects of interfacial phenomena. In addition, SAMs comprise an...
متن کاملElectrochemical reactions of pincer rhodium(I) complexes
The electrochemical properties of the (PCP)Rh(H2) (1-H2, PCP 1⁄4 k-C6H3e2,6-(CH2P(Bu2)) complex was examined by cyclic voltammetry in acetonitrile (MeCN), dimethylsulfoxide (DMSO) and 1,2difluorobenzene (1,2-DFB). Upon oxidation in weakly or non-coordinating media such as 0.05 M NaBAr24 in 1,2-difluorobenzene, simple one electron oxidation to [(PCP)RhII(H2)]þ is observed. Conversely, in coordin...
متن کاملMass spectrometric snapshots for electrochemical reactions.
A hybrid ultramicroelectrode containing one micro-carbon electrode and one empty micro-channel was employed to be a micro-electrochemical cell and a mass spectrometric nanospray emitter. This setup can combine MS with an electrode directly and provide in situ information about an electrochemical reaction. The mechanisms proposed by Bard et al. for a Ru(bpy)32+ (bpy = 2,2'-bipyridine) electroche...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Nature
سال: 1964
ISSN: 0028-0836,1476-4687
DOI: 10.1038/202738a0